Bookcover of Reactivity of Organic Molecules at Single-Crystal Surfaces of Pt
Booktitle:

Reactivity of Organic Molecules at Single-Crystal Surfaces of Pt

Electrosorption and Surface Reactivity, Molecules, Investigations

VDM Verlag Dr. Müller (2009-09-20 )

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ISBN-13:

978-3-639-19465-4

ISBN-10:
3639194659
EAN:
9783639194654
Book language:
English
Blurb/Shorttext:
Studies of the electrochemical adsorption and reactivity of small organic molecules at well- ordered Pt single-crystal surfaces in the region of underpotential deposition (UPD) of H have become a major activity in current electrochemical surface science. This work presents investigation of the processes of electrosorption of guanidonium (and structurally related) molecule-ions and the Faradaic reduction of two aliphatic oximes (formamidoxime and acetaldehyde oxime), at major Pt single-crystal planes. The results reveal remarkable specificities to Pt surface geometry upon adsorption and reactivity of these small molecules, observed in various electrolytic media. Application of two major electrochemical techniques and a complementary in situ FTIR spectroscopy method enables a thorough understanding of the mechanism of these unique surface electrochemical reactions. This work should be useful not only to professionals directly involved in electrochemistry of single-crystal electrodes, but also to all those working (and studying) in the field of applied electrochemistry, including fuel cell and battery-related processes.
Publishing house:
VDM Verlag Dr. Müller
Website:
http://www.vdm-verlag.de
By (author) :
BOGUSLAW PIEROZYNSKI
Number of pages:
192
Published at:
2009-09-20
Stock:
Available
Category:
Chemistry
Price:
68.00 €
Keywords:
Pt single-crystals, electrosorption, surface reactivity, molecule-ions, oximes, cyclic voltammetry, impedance spectroscopy, UPD of H, co-adsorption of anions

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