Thermodynamic versus Kinetic Reaction Control
978-613-1-01217-4
6131012172
76
2013-05-21
34.00 €
eng
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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. The distinction (also known as selectivity) between kinetically or thermodynamically controlled chemical reaction pathways is relevant when product A forms faster (which is called the kinetically controlled product) than product B because the activation energy for product A is lower than that for product B, yet product B is more stable (this is called the thermodynamically controlled product). The conditions of the reaction, such as temperature, pressure, or solvent, affect which reaction pathway may be favored: either the kinetically controlled or the thermodynamically controlled one. Note this is only true if the activation energy of the two pathways differ, with one pathway having a lower Ea (energy of activation) than the other.
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